Publications
19. Hydrocyanation in Organic Synthesis. Comprehensive Organic Synthesis, 3rd Ed. Accepted. [Book Chapter]
Lin,S; Schuppe, A. W.​​
Jiao, Z.; Jaunich, K. T..; Tao, T.; Gottschall, O.; Hughes. M. M.; Turlik, A.; Schuppe, A. W.
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highlighted in synfacts
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Prior to Vanderbilt:
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17. A General Strategy for the Asymmetric Preparation of α-Stereogenic Allyl Silanes, Germanes, and Boronate Esters via Dual Copper Hydride- and Palladium-Catalysis. Angew. Chem. Int. Ed. 2022, 61, e202212630.
Knippel, J. L.; Ni, A. Z.; Schuppe, A. W.; Buchwald, S. L.
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Losacco, G.L.; Bennett, R.; Ahmad, I. A. H.; Barrientos, R. C.; DaSilva, J. O.; Dong, Y.; Schuppe, A. W.; Wang, Z.; Aiken, S.; Mangion, I.; Aggarwal, V. K.; Regalado, E. L.
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15. Unified Total Synthesis of The Limonoid Alkaloids: Strategies for the Synthesis of Highly Substituted Pyridine Scaffolds. Chem 2022, 8, 2856−2887. (preprint)
Schuppe, A. W.; Liu, Y.; Zhao, Y.; Wang, E.; Lee, J.; Ibarraran, S.; Huang, D.; Loria, J. P.; Newhouse, T. R.
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14. Synthesis of melazolide B, a degraded limonoid and related compounds. Tetrahedron Chem 2022, 100011. (preprint)
Liu, Y.; Schuppe, A. W.; Zhao, Y.; Lee, J.; Newhouse, T. R.
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13. Confronting the Challenging Asymmetric Carbonyl 1,2-Addition using Vinyl Heteroarene Pronucleophiles: Ligand-Controlled Regiodivergent Processes Through a Dearomatized Allyl-Cu Species. J. Am. Chem. Soc. 2022, 144, 5985–5995.
Dong, Y.; Schuppe, A. W.; Mai, B. K.; Liu, P.; Buchwald, S. L.
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12. A Dual CuH- and Pd-catalyzed Stereoselective Synthesis of Highly Substituted 1,3-Dienes. Org. Lett. 2021, 23, 8816−8821.
Hou, C.-J.; Schuppe, A. W.; Knippel, J. L.; Ni, A. Z.; Buchwald, S. L.
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11. Enantioselective Hydroalkenylation of Olefins with Enol Sulfonates Enabled by Dual Copper Hydride and Palladium Catalysis. J. Am. Chem. Soc. 2021,143, 5330−5335.
Schuppe, A. W.; Knippel, J. L.; Borrajo-Calleja, G. M.; Buchwald, S. L.
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10. An invocation for computational evaluation of isomerization transforms: cationic skeletal reorganizations as a case study. Nat. Prod. Rep. 2021,38, 510−527.
Schuppe, A. W.; Liu, Y.; Newhouse, T. R.
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9. An Improved Process for the Palladium-Catalyzed C–O Cross-Coupling of Secondary Alcohols. Org. Lett. 2020,14, 5369−5374.
Zhang, H.; Ruiz-Castillo, P.; Schuppe, A. W.; Buchwald, S. L.
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8. Enantioselective Olefin Hydrocyanation without Cyanide. J. Am. Chem. Soc. 2019,141,18668–18672.
Schuppe, A. W.; Borrajo-Calleja, G. M.; Buchwald, S. L.
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7. Total Synthesis of (+)-Granatumine A and Related Bislactone Limonoid Alkaloids via a Pyran to Pyridine Interconversion. J. Am. Chem. Soc. 2019, 141, 9191–9196.
Schuppe, A. W.; Zhao, Y.; Liu, Y.; Newhouse, T. R.
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6. Copper-Catalyzed Vinylogous Aerobic Oxidation of Unsaturated Compounds with Air. J. Am. Chem. Soc. 2018,140, 5300–5310.
Zhang, H.-J.; Schuppe, A. W.; Pan, S.-T.; Chen, J.-X.; Wang, B.-R.; Newhouse, T. R.; Yin, L.
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5. Total Synthesis of (–)-Xylogranatopyridine B via a Palladium-Catalyzed Oxidative Stannylation of Enones. J. Am. Chem. Soc. 2018,140, 2062–2066.
Schuppe, A. W.; Huang, D.; Chen, Y.; Newhouse, T. R.
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4. Scalable synthesis of enaminones utilizing Gold's reagents. Tetrahedron 2017,73, 3643–3651.
Schuppe, A. W.; Cabrera, J. C.; McGeoch, C. L.; Newhouse, T. R.
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3. Assembly of the Limonoid Architecture by a Divergent Approach: Total Synthesis of (±)-Andirolide N via (±)-8α-Hydroxycarapin. J. Am. Chem. Soc. 2017,139, 631–634.
Schuppe, A. W.; Newhouse, T. R.
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2. Scalable Procedure for the Fragmentation of Hydroperoxides Mediated by Copper and Iron Tetrafluoroborate Salts. Org. Biomol. Chem. 2016,14, 6197–6200.
Huang, D.; Schuppe, A. W.; Liang, M. Z.; Newhouse, T. R.
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1. Computational and Experimental Studies of Phthaloyl Peroxide-Mediated Hydroxylation of Arenes Yield a More Reactive Derivative, 4,5-Dichlorophthaloyl Peroxide. J. Org. Chem. 2015,80, 8084–8095.
Camelio, A. M.; Liang, Y.; Eliasen, A. M.; Johnson, T. C.; Yuan, C.; Schuppe, A. W.; Houk, K. N.; Siegel, D.
